This was just playing around because it looked fun...

Test #1:

KClO₃ (potassium chlorate)/sucrose (table sugar) ignited with a drop of H₂SO₄ (sulfuric acid). I just mixed the KClO₃/sucrose in fairly equal amounts, with a bit more KClO₃, I just wanted it to ignite, I wasn't worried about getting the perfect ratios.

Powder and acid:

Ignition a few seconds after adding acid:

Residue after suggesting a rather inefficient mixture:

Test #2:

KMnO₄ (potassium permanganate) ignited with glycerine. The reaction takes more or less time depending on ambient temperature and how fine the KMnO₄ crystals are.

5g KMnO₄:

Burning (some of the flame is from the paper it was in because the wood was a bit wet):

KMnO₄ does a good job of staining things, and pouring water on the stuff once it went out made this nice mess:

I have videos, but they aren't all that good. Rat_Bastard has better ones that will be up in his section eventually.